中南大学学报(自然科学版)2024,Vol.55Issue(11) :4226-4235.DOI:10.11817/j.issn.1672-7207.2024.11.019

蒙脱土基催化材料改性沥青混合料路用性能及其催化性能评价

Pavement performance and catalytic performance evaluation of montmorillonite-based catalytic material modified asphalt mixture

金娇 陈晖文 张扮 刘帅 饶如意 李锐
中南大学学报(自然科学版)2024,Vol.55Issue(11) :4226-4235.DOI:10.11817/j.issn.1672-7207.2024.11.019

蒙脱土基催化材料改性沥青混合料路用性能及其催化性能评价

Pavement performance and catalytic performance evaluation of montmorillonite-based catalytic material modified asphalt mixture

金娇 1陈晖文 2张扮 2刘帅 2饶如意 2李锐2
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作者信息

  • 1. 长沙理工大学交通运输工程学院,湖南长沙,410114;公路养护技术国家工程研究中心,湖南长沙,410114
  • 2. 长沙理工大学交通运输工程学院,湖南长沙,410114
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摘要

以石墨相氮化碳(g-C3N4)作为降解汽车尾气的光催化剂,将蒙脱土有机化处理后与三聚氰胺结合制备光催化复合材料(CNM),探讨g-C3N4和CNM的吸光特性和微观结构.制备g-C3N4和CNM改性沥青混合料,研究改性沥青混合料的高温稳定性、低温抗裂性和水稳定性,并探索g-C3N4和CNM改性剂及其改性沥青混合料对NO、CO和HC的光催化降解效果.研究结果表明:CNM在全波段范围内吸光度比g-C3N4的大,在波长为300~480 nm范围内吸光度显著提升;g-C3N4和CNM改性沥青混合料高温稳定性和水稳定性得到提升,且低温抗裂性满足规范要求;g-C3N4和CNM改性剂及其改性沥青混合料对NO的降解效果优于CO和HC对NO的降解效果,且CNM的降解效率高于g-C3N4的降解效率.

Abstract

Graphitic carbon nitride(g-C3N4) was selected as a photocatalyst for the degradation of automobile exhaust. Montmorillonite(DAC-OMMT) was combined with melamine to prepare photocatalytic composites (CNM). The g-C3N4 and CNM-modified asphalt mixtures were prepared. The high-temperature stability,low-temperature crack resistance,and water stability of the modified asphalt mixtures were studied. The photocatalytic degradation effects of g-C3N4 and CNM modifiers and their modified asphalt mixtures on NO,CO,and HC were explored. The results show that the absorbance of CNM is bigger than that of g-C3N4 in the whole wavelength range and is remarkably improved in the wavelength range of 300-480 nm. The high-temperature stability and water stability of two types of modified asphalt mixtures are improved,and the low-temperature crack resistance meets the requirements of the specification. The degradation effect of g-C3N4 and CNM modifiers and their modified asphalt mixtures on NO is better than that of CO and HC,and the degradation efficiency of CNM is better than that of g-C3N4.

关键词

蒙脱土/石墨相氮化碳/沥青混合料/汽车尾气/光催化降解

Key words

montmorillonite/graphite carbon nitride/asphalt mixture/automobile exhaust/photocatalytic degradation

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出版年

2024
中南大学学报(自然科学版)
中南大学

中南大学学报(自然科学版)

CSTPCDCSCD北大核心
影响因子:0.938
ISSN:1672-7207
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