In this work,two different types of β-substituted thioethers are synthesized with high yields from simple alkenes and thiophenols.The products of this reaction could be controlled by the solvent.When anhydrous acetonitrile was used as the solvent,β-chloro-substituted thioethers were obtained in medium to high yields.When using dimethyl sulfoxide,β-hydroxyl-substituted thioethers generated alternatively.Moreover,this novel approach features the advantages of wide substrate scope,good functional group tolerance,simple operation,and mild response conditions.
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