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从阳极氧化废磷酸中回收磷资源工艺研究

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以阳极氧化废磷酸为原料,与羟基氧化铁反应回收磷得到磷酸铁,通过单因素变量优化实验确定最佳生产条件.实验结果表明:阳极氧化废磷酸稀释到磷酸质量分数为8.00%,按照磷铁物质的量比1.0∶1.1加入羟基氧化铁,反应温度为95 ℃,反应2h,磷酸回收率达到95.99%,回收的磷酸铁可用作其他高价值产品原料.
Phosphorous recovery study from anodized waste phosphoric acid
Anodized Waste Phosphoric Acid was studied and reacted with hydroxyferroic oxide,which recovery phosphorous and synthetize iron phosphate,the optimal production conditions were determined with some single-factor-optimization-experiments.The results show that anodized waste phosphoric acid was diluted to a mass concentration of 8.00%phosphoric acid,the addictive amount of hydroxyferroic oxide was followed with that the mole ration of phosphorus and ferrum is 1.0∶1.1,the reaction temperature was 95 ℃,and the reaction time was 2 h,the recovery efficiency of phosphoric acid reached to 95.99%,the recovered iron phosphate can be used as a raw material for other high-value products.

anodized waste phosphoric acidhydroxyferroic oxideiron phosphate

冯伟、宋德生、潘建华、罗莉娟

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斯瑞尔环境科技股份有限公司,广东惠州 516000

阳极氧化废磷酸 羟基氧化铁 磷酸铁

2024

再生资源与循环经济
天津再生资源研究所 中国再生资源回收利用协会

再生资源与循环经济

影响因子:0.367
ISSN:1674-0912
年,卷(期):2024.17(11)