首页|(Ti1/4Zr1/4V1/4Nb1/4)Alx高熵金属间化合物合金的组织结构研究

(Ti1/4Zr1/4V1/4Nb1/4)Alx高熵金属间化合物合金的组织结构研究

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设计并用真空电弧熔炼法制备了五主元(Ti1/4Zr1/4V1/4Nb1/4)Alx高熵金属间化合物合金,研究了铸态及高温退火后合金的晶体结构、显微组织及硬度的变化。结果表明,(Ti1/4Zr1/4V1/4Nb1/4)Alx高熵金属间化合物合金以D022有序化合物结构为基体,夹杂少量的L10析出相。合金组织为树枝晶组织,由于枝晶相和枝晶间相的元素分布不同,使合金产生了相分离现象。(Ti1/4Zr1/4V1/4Nb1/4)Al3。5合金中L1。相含量最少,并且在1 300 ℃热处理后基本消失,合金转变为完全由有序的D022相组成。此合金在1 400℃高温下仍能保持铸态的基体结构,没有析出其他相,表明此合金具有极好的高温热稳定性。
Study on Microstructure and Crystal Structure of(Ti1/4Zr1/4V1/4Nb1/4)Alx High Entropy Intermetallic Compounds
Five principal-element(Ti1/4Zr1/4V1/4Nb1/4)Alx high-entropy intermetallic compounds were designed and prepared by vacuum arc melting method.The changes in crystal structures,microstructures and hardnesses of as-cast and high-temperature annealed alloys were investigated in detail.The results indicated that the(Ti1/4Zr1/4V1/4Nb1/4)Alx high entropy intermetallic compounds were based on ordered D022 structure with a small amount of L10 precipitates.The alloys'microstructure was a dendritic structure.Because of the different distribution of elements in dendritic and interdendritic regions,phase separation phenomenon occurs in the alloys.The(Ti1/4Zr1/4V1/4Nb1/4)Al3.5 alloy had the least content of L10 phase,which basically disappeared after heat treatment at 1 300 ℃.This alloy could still maintain its as-cast matrix structure at a high temperature up to 1 400 ℃ without precipitation of other phases,indicating that it had excellent high-temperature thermal stability.

high entropy alloyintermetallic compoundsheat treatmentmicrostructurecrystal structure

覃业恒、张越、张骁、杨程、陈迅、王乔、赵鹏程、刘亮

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辽宁工业大学材料科学与工程学院,辽宁锦州 121001

高熵合金 金属间化合物 热处理 显微组织 晶体结构

2024

铸造
沈阳铸造研究所 中国机械工程学会铸造分会

铸造

CSTPCD
影响因子:0.499
ISSN:1001-4977
年,卷(期):2024.73(8)