首页|铸造除尘灰基地质聚合物制备及性能

铸造除尘灰基地质聚合物制备及性能

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以铸造除尘灰、水玻璃为原料,采用压制成形法制备除尘灰基地质聚合物。通过单因素试验和正交试验,研究铸造除尘灰比例、水灰比、水玻璃浓度和模数、成形压力等因素对地质聚合物抗压强度的影响,采用扫描电镜和能谱分析对地质聚合物的微观形貌和成分进行了表征。结果表明:除尘灰基地质聚合物抗压强度随成形压力增加而上升,随水灰比、水玻璃浓度和模数的增加先上升后下降;各因素影响大小依次为水玻璃模数>成形压力>水灰比>水玻璃浓度,最优参数为水灰比17%,水玻璃浓度38%,模数1。3,成形压力60 MPa,28天抗压强度可达19。46 MPa;低模数水玻璃促进了凝胶相的产生,高成形压力使试样内部结构更致密,提高了铸造除尘灰基地质聚合物的抗压强度。
Preparation and Properties of Foundry Dust Based Geopolymer
Geopolymer was prepared by the compression molding method using foundry dust and water glass as raw materials.The effects of foundry dust ratio,water-to-ash ratio,water glass concentration and modulus,and molding pressure on the compressive strength of foundry dust based geopolymer are studied through single-factor experiments and orthogonal experiments.Scanning electron microscopy and energy spectrum analysis are conducted to characterize the microscopic morphology and composition of the geopolymer.The study shows that the compressive strength of foundry dust based geopolymer increases with the increase of molding pressure,and initially increases and then decreases with the increase of water-to-ash ratio,water glass concentration,and modulus.The magnitude of the influence of each factor is as follows:water glass modulus>molding pressure>water-to-ash ratio>water glass concentration.The optimal parameters are water-to-ash ratio of 17%,water glass concentration of 38%,modulus of 1.3,molding pressure of 60 MPa,and compressive strength of 19.46 MPa after 28 days.The low modulus of water glass promoted the formation of gel phase,and the high molding pressure made the internal structure of the sample more compact,thus improving the compressive strength of the foundry dust based geopolymer.

solid waste utilizationfoundry dustpress forminggeopolymerswater glass

张宇航、樊索、龚小龙、冯广海

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武汉工程大学机电工程学院,湖北武汉 430073

华中科技大学材料成形与模具技术国家重点实验室,湖北武汉 430074

固废利用 铸造除尘灰 压制成形 地质聚合物 水玻璃

2024

铸造
沈阳铸造研究所 中国机械工程学会铸造分会

铸造

CSTPCD
影响因子:0.499
ISSN:1001-4977
年,卷(期):2024.73(11)