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固体硫酸脲的研究

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研究了硫酸脲制备过程中可控主要因素的影响以及固体硫酸脲的晶体形状、X射线衍射图、吸湿性和水溶液的酸性.实验表明,硫酸脲制备过程中的主要影响因素为:尿素、硫酸的比例、反应温度及硫酸浓度等,其中n(尿素)∶n(硫酸)=2∶1,反应温度为80℃,硫酸质量分数为95%~98%,显微镜下观测其晶体呈六棱柱状.X射线衍射图表明:生成物与可能生成的物质的X射线衍射图完全不同,吸湿性与时间呈直线关系,水溶液的酸性较同等浓度的硫酸弱而比柠檬酸强.以上反应条件下可以制备出性质稳定、成本较低的固体硫酸脲.
Study on Solid Urea Sulfate
The controlled main influence factors and crystal shape of urea sulfate, XRD, hygroscopy and acidity in water in urea sulfate production are studied. The result indicates that the main effect factors are ratio of urea and sulfuric acid, reaction temperature, concentration of sulfuric acid, and the optimization are 2:1, 80℃, 95% ~ 98 % respectively. The crystal shape of urea sulfate examined under microscope is hexagonal, the XRD is different from likely productions, the hygroscopy is linear, and the acidity at same concentration is weaker than sulfuric acid, but stronger than citric acid. In the reaction conditions above, urea sulfate with stable qualities, low cost can be got. All of these can be used as references to theoretical research and industrialization application.

urea sulfateproductioninfluence factorphysical characteristic

王光龙、张芳军、张宝林

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郑州大学化工学院,河南,郑州,450001

硫酸脲 制备 影响因素 物性

河南省自然科学基金

0611021300

2006

郑州大学学报(工学版)
郑州大学

郑州大学学报(工学版)

CSTPCDCSCD
影响因子:0.442
ISSN:1671-6833
年,卷(期):2006.27(4)
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