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热循环条件下SLM-TC4钛合金α′马氏体的快速分解

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马氏体是选区激光熔化TC4 的常见物相,其分解过程调控对优化成形件性能尤为重要。采用激光扫描SLM-TC4 全α′马氏体试样,对沉积态试样施加不同热循环,结合数值模拟分析不同热循环条件下的α′马氏体相变序列,明确了α′→β 高温→(α+β)与α′→(α+β)两种转变路径及其组织特征,前者的α相不再具有α′的层级结构,而表现为魏氏集束与网篮组织的混合形态,后者的α相继承了马氏体的晶体取向和层级结构。在第二种转变路径条件下,当热循环温度逼近β转变温度且峰谷温差值较大时,α′马氏体可以在较短时间内依赖孪晶界完成分解,进而形成细小的球化α相,有助于选区激光熔化TC4 合金的性能提升。
Rapid Decomposition of Martensite in SLM-TC4 Titanium Alloy under Thermal Cycling Conditions
α′ martensite is the major phase in selective laser melted TC4 alloy,and the controlling of its decomposition is very important for the optimization of the formed components.Laser scanning was applied to the SLM-TC4 samples with full α′ martensite microstructure,the thermal history curves at different locations of the samples were derived with the aid of numerical simulations,and the phase transformation sequence of α′ martensite under thermal cycling conditions was analysed.Two transformation pathways are identified:α′→β→(α+β)and α′→(α+β),with different thermal histories.In the former pathway,the α phase no longer maintains the hierarchical structure of α′,which typically exhibits a mixed morphology of Widmanstätten colonies and basketweave structures.In the latter pathway,the α phase retains the crystallographic orientation and hierarchical structure of the martensite.It has also been shown that in the second transformation pathway,when the temperature of thermal cycling approaches βtr and the temperature difference between the peak and valley is significant,the decomposition of α′martensite and the globalization of the α phase are accelerated,with β precipitating at the twin boundaries,which can further contribute to the enhancement of the properties of the SLM TC4 components.

TC4 titanium alloythermal cyclingα′ martensite decompositionmicrostructure

咸舒凡、王嘉鑫、郭家宝、周峻锋、王前、王猛

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西北工业大学凝固技术国家重点实验室,陕西 西安 710072

西北工业大学金属高性能增材制造与创新设计工业和信息化部重点实验室,陕西 西安 710072

TC4钛合金 热循环 α′马氏体分解 微观组织

2025

铸造技术
西安市科学技术协会

铸造技术

影响因子:0.458
ISSN:1000-8365
年,卷(期):2025.46(1)