首页|Cu-Ni-Si-xLa热轧板电导率与其特征组织的关联机制

Cu-Ni-Si-xLa热轧板电导率与其特征组织的关联机制

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为探究稀土La元素的添加对C70250 合金组织和性能的作用,利用金相显微镜、扫描电镜、电子背散射衍射、显微硬度仪、电导率仪及拉伸试验机等研究了Cu-Ni-Si-xLa合金在铸态、均匀化态、热轧态的显微组织、晶粒大小及分布和析出相的演变过程,分析前处理过程中不同稀土La含量对合金性能的影响规律。结果表明,添加La在铸锭靠外的区域会出现细晶区域,这个细晶区的晶粒随着La含量的增加先细化再粗化;Base合金和添加 0。05%La(质量分数)合金出现明显的树枝晶,晶界较为模糊。铸锭中加入适量La元素后,产生细晶强化效果,硬度升高。Base合金中再结晶晶粒分布于纤维状晶粒宽度方向两侧,而加入La合金再结晶晶粒多分布于纤维状晶粒端部并有向晶粒中间生长的趋势,再结晶晶粒会切断纤维状晶粒使其变短。适量La的添加可提高Cu-2。8Ni-0。66Si合金的轧制态强度,综合性能最好的是La的加入量为 0。2%,抗拉强度和电导率分别为 441 MPa和 18。2%IACS。
Mechanism of the Correlation between the Electrical Conductivity of the Cu-Ni-Si-xLa Hot-rolled Sheets and their Characteristic Microstructures
To investigate the effects of La addition on the microstructure and properties of C70250 alloys,the microstructure,grain size and distribution,and evolution of precipitates in Cu-Ni-Si-xLa alloys in the cast,homogenized,and hot-rolled states were investigated via optical microscope,scanning electron microscope,electron backscatter diffraction,microhardness testing,electrical conductivity testing,and tensile testing.The influence of different La contents on the alloy performance before processing was analysed.The results show that the addition of La in the outer region of the cast ingot results in the formation of a fine-grained region,and the grain size of this region first refines and then coarsens with increasing La content.The dendritic structure is obvious in the Base alloy and alloy with 0.05 wt.%La added,and the grain boundaries are blurred.After a suitable amount of La is added to the cast ingot,a fine-grain strengthening effect is produced,and the hardness increases.In the Base alloy,the recrystallized grains are distributed on both sides in the width direction of the fibrous grains.However,in the alloy with La added,the recrystallized grains are mostly distributed at the ends of the fibrous grains and tend to grow towards the middle of the grains.The recrystallized grains sever the fibrous grains,thereby leading to a reduction in their length.The addition of an appropriate amount of La improves the hot-rolled strength of the Cu-2.8Ni-0.66Si alloy,and the best comprehensive performance is obtained when the addition of 0.2 wt.%La,with a tensile strength of 441 MPa and an electrical conductivity of 18.2%IACS.

Cu-Ni-Si-xLa alloypretreatmentfine grain strengtheningmicrohardnesstensile strengthelectrical conductivity

高博阳、李勇、邹航、王艺蕾、钱晓明、郭慧稳

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东北大学轧制技术及连轧自动化国家重点实验室,辽宁 沈阳 110819

燕山大学国家冷轧板带装备及工艺工程技术研究中心,河北 秦皇岛 066000

中铝洛阳铜加工有限公司,河南 洛阳 471039

Cu-Ni-Si-xLa合金 前处理 细晶强化 显微硬度 抗拉强度 电导率

2025

铸造技术
西安市科学技术协会

铸造技术

影响因子:0.458
ISSN:1000-8365
年,卷(期):2025.46(1)