造纸科学与技术2024,Vol.43Issue(8) :41-45,50.DOI:10.19696/j.issn1671-4571.2024.8.009

脱酸加固技术在脆化纸质文物修复中的应用研究

Research on the Application of Acid Removal and Reinforcement Technology in the Restoration of Fragile Paper Cultural Relics

黄燕 陈家欣
造纸科学与技术2024,Vol.43Issue(8) :41-45,50.DOI:10.19696/j.issn1671-4571.2024.8.009

脱酸加固技术在脆化纸质文物修复中的应用研究

Research on the Application of Acid Removal and Reinforcement Technology in the Restoration of Fragile Paper Cultural Relics

黄燕 1陈家欣2
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作者信息

  • 1. 佛山市祖庙博物馆 文物保护部,广东 佛山,528000
  • 2. 佛山市祖庙博物馆,广东 佛山,528000
  • 折叠

摘要

脆化纸质文物增强处理过程中,主要依靠纤维原位接枝技术对纸质进行修复,未考虑老化的根本原因,使修复后纸质的撕裂指数依旧较高.因此,提出将脱酸加固技术应用到脆化纸质文物修复过程中.首先利用Kirsch算子分析多角度拍摄的脆化纸质文物图像,获取边缘特征并计算出图像边缘强度,与参考图像进行对比,检测文物表面污损;其次,应用激光清洁技术对文物纸质表面产生热冲击,清除纳米级污染物微粒;再次,借助大气压非平衡等离子体结构,将脱酸剂溶液中的OH-离子转移到纸质上,与酸性物质中和实现文物脱酸修复;最后,运用离心静电纺丝设备将聚偏二氟乙烯材料转化为纤维,覆盖到脱酸修复后的文物上,达到加固脆化纸质文物的目的.实验结果表明:应用脱酸加固技术实现脆化纸质文物修复后,进行为期 18 天的紫外老化处理,纸质的撕裂指数为1.5mN·m2·g-1,更好地满足了文物保护要求.

Abstract

In the process of enhancing the treatment of brittle paper cultural relics,the repair of paper mainly relies on fiber in-situ grafting technology,without considering the root cause of aging,resulting in a high tear index of the repaired paper.Therefore,it is proposed to apply deacidification reinforcement technology to the restoration process of brittle paper cultural relics.Using Kirsch operator to analyze brittle paper cultural relics images captured from multiple angles,obtaining edge features and calculating image edge strength,and comparing with reference images to detect surface fouling of cultural relics.Applying laser cleaning technology to generate thermal shock on the surface of cultural relics paper,removing nanoscale pollutant particles.By utilizing the atmospheric pressure non-equilibrium plasma structure,OH-ions in the deacidifying agent solution are transferred to paper and neutralized with acidic substances to achieve acid removal and restoration of cultural relics.Finally,using centrifugal electrospinning equipment,the polyvinylidene fluoride material is converted into fibers and covered on the restored cultural relics after acid removal,achieving the goal of reinforcing brittle paper cultural relics.The experimental results show that after using deacidification reinforcement technology to restore brittle paper cultural relics,the paper undergoes 18 days of UV aging treatment,and the tear index of the paper is 1.5mN·m2·g-1,which better meets the requirements of cultural relics protection.

关键词

脱酸加固/纸质文物/清洁/等离子体放电/离心静电纺丝/修复

Key words

deacidification reinforcement/paper cultural relics/cleaning/plasma discharge/centrifugal electrospinning/repair

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基金项目

青年科学基金项目(72204153)

出版年

2024
造纸科学与技术
广东省造纸学会 广东省造纸研究所

造纸科学与技术

CSTPCD
影响因子:0.269
ISSN:1671-4571
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