造纸科学与技术2024,Vol.43Issue(9) :19-25,31.DOI:10.19696/j.issn1671-4571.2024.9.005

纤维素基电磁屏蔽气凝胶的制备与性能研究

Preparation and Properties of Cellulose Based Electromagnetic Shielding Aerogel

程栋 马强 段超
造纸科学与技术2024,Vol.43Issue(9) :19-25,31.DOI:10.19696/j.issn1671-4571.2024.9.005

纤维素基电磁屏蔽气凝胶的制备与性能研究

Preparation and Properties of Cellulose Based Electromagnetic Shielding Aerogel

程栋 1马强 2段超2
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作者信息

  • 1. 广东冠豪新材料研发有限公司,广东广州,511466
  • 2. 陕西科技大学轻工科学与工程学院,陕西西安,710021
  • 折叠

摘要

近年来,电磁波污染受到了人们的广泛关注,因而构建轻质、高效的电磁屏蔽功能材料成为研究热点.基于此,以纳米纤维素(CNF)为基材,MXene(简称M)和聚吡咯(PPy,简称P)作为导电填料,磁性铁氧体(NiFe2O4,简称NF)作为磁性填料,通过原位生长的方法和定向冷冻干燥技术,制备出三维的电磁屏蔽气凝胶(M-NF/P@CNF),通过调控NiFe2O4与MXene的质量比来探究对电磁屏蔽性能的影响.研究结果表明:对上述复合气凝胶纵向方向上,当M:NF质量比为2∶1时,其总屏蔽效能达到81.85 dB,其中吸收损耗可达到77.82 dB;而对横向方向,当M:NF质量比为3∶1,其总屏蔽效能和吸收损耗最佳,分别达到83.14 dB和78.09 dB.这为纤维素基电磁屏蔽材料的设计提供了新的思路及合成策略,对开发纤维素材料在高附加值方面的应用有重要的意义.

Abstract

In recent years,electromagnetic interference (EMI) pollution has received widespread attention,making it a great research hotspot to prepare lightweight and excellent electromagnetic interference shielding (EMIS) materials. In this study,a 3D EMIS aerogel,namely M-NF/P@CNF was prepared via in-situ growth method and directional freeze-drying technology. The as-prepared M-NF/P@CNF aerogel consisted of cellulose nanofibril (CNF) as a substrate,MXene (M) and polypyrrole (P) as conductive fillers and magnetic ferrite (NiFe2O4,NF) as magnetic fillers. We investigated the effect of the mass ratio of NiFe2O4 to MXene on EMIS performance. Results showed that when the mass ratio of NiFe2O4 and MXene was 1∶2,the total shielding efficiency (SET) of the horizontal direction of M2-NF1/P@CNF aerogel reached 81.85 dB,the absorption loss (SEA) was as high as 77.82 dB,while the vertical direction M3-NF1/P@CNF aerogel had the highest SET (83.14 dB) and SEA (78.09 dB).This study provides a new idea and synthesis strategy for the design of cellulose-based EMIS materials,which is of great significance for the development of cellulosic materials in high value-added applications.

关键词

纳米纤维素/电磁屏蔽/MXene/磁性铁氧体/气凝胶

Key words

nanocellulose/electromagnetic shielding/MXene/magnetic ferrite/aerogel

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出版年

2024
造纸科学与技术
广东省造纸学会 广东省造纸研究所

造纸科学与技术

CSTPCD
影响因子:0.269
ISSN:1671-4571
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