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南川地区陶粒页岩地质特征及煅烧制度研究

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陶粒产量不足是这一多功能矿物材料大规模、持续性应用于绿色建材领域的瓶颈.以重庆南川地区富页岩层位为对象,研究区龙马溪组(S1l)中下部页岩在煅烧试验后膨胀系数N平均=4.1(边界品位N>2).基于XRF、岩矿鉴定、SEM扫描电镜显示具膨胀性页岩特征,w(SiO2)约为62%、w(Al2O3)约为 19%、w(Fe2O3)约为 7%、w(CaO+MgO+K2O+Na2O)约为 8.5%、TOC 约为 0.86%,矿物组合特征为石英+绿泥石+伊利石+斜长石,制备的页岩陶粒矿物组合为石英+赤铁矿+变质矿物.页岩矿物颗粒的定向排列和特殊结构对膨胀性具有促进作用.根据正交试验、单因素变量控制试验优化研究区煅烧制度为:粒径12~15 mm、升温速率12℃/min、煅烧温度1 200 ℃、保温时间20 min.研究可为区内陶粒用页岩矿产资源的开发利用提供参考.
Research on geological characteristics and calcination system of ceramsite shale in Nanchuan area
The insufficient output of ceramsite has become the bottleneck restricting the scale and sustainable application of this multi-functional mineral material in the building materials market.Through taking the rich shale horizon in Nanchuan area of Chongqing as the object,it was found that the middle and lower shale of Longmaxi Formation(S1 l)in the study area had an average expansion coefficient of N=4.1 after calcination test(boundary grade N>2).Based on XRF,rock and mineral identification and SEM scanning electron mi-croscopy,the characteristics of expansive shale are shown to be w(SiO2)62%,w(Al2O3)19%,w(Fe2O3)7%,w(CaO+MgO+K2O+Na2O3)8.5%,TOC of approximately 0.86%,and the mineral assemblage is characterized by quartz,chlorite,illite and plagioclase,and the prepared shale ceramsite mineral assemblage is quartz,hematite and metamorphic minerals.The directional arrangement and special structure of mineral particles in shale can significantly promote the expansibility.According to the orthogonal test and single fac-tor variable control test,the calcination system in the study area is optimized as follows:particle size 12~15 mm,heating rate 12 ℃/min,calcination temperature 1 200 ℃,and holding time 20 min.It is hoped that this study can provide a basis for the development and utilization of ceramsite shale mineral resources in the study area.

ceramsite shale mineral resourcesLongmaxi Formationorthogonal testcalcination system

郭宇、牟佳佳、李勇、周琴、罗航

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重庆市地质矿产勘查开发局107地质队,重庆 401120

长江师范学院 土木建筑工程学院,重庆 408100

陶粒页岩矿产资源 龙马溪组 正交试验 煅烧制度

重庆市规划和自然资源局科技项目重庆市教委科学技术研究项目重庆市大学生创新创业训练计划项目

KJ-2021035KJQN202101434S202210647024

2024

能源与环保
河南省煤炭科学研究院有限公司 河南省煤炭学会

能源与环保

CSTPCD
影响因子:0.221
ISSN:1003-0506
年,卷(期):2024.46(1)
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