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北京房山煤矿区土壤重金属元素地球化学分布特征及源解析

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房山煤矿区有百年的煤矿开采历史,可能会对周边生态环境造成污染.为了评估房山煤矿区土壤环境状况,在房山周口店地区选取了最具代表性的矿区作为研究区域,采集196件表层土样和40件深层土样,对土样中重金属元素As、Cd、Cr、Hg、Ni、Pb、Zn的含量进行了测试分析.运用数理统计、聚类分析、因子分析、空间分布分析相结合的方法研究了房山煤矿区土壤重金属元素的表层和深层分布特征,并对其来源进行了探讨.结果表明,研究区内重金属元素平均值普遍高于北京市区域背景值,Hg元素尤其明显;表层土壤中除Hg、Cd、As外,其他元素分布较均匀;除Pb、Zn元素外,其他元素在深层土壤中的富集系数普遍大于表层土壤;通过相关性分析和聚类分析可知,Cr和Ni,Hg和Pb、Cd和Zn的来源可能相同.土壤母质和自然成土过程可能是影响土壤中Cr和Ni元素分布特征的主要原因,工业矿业活动可能是Cd和Zn元素含量偏高的原因,地质背景叠加人类活动可能是影响Hg和Pb元素分布的原因;从空间分布情况来看,水平方向上研究区北部的重金属元素含量较南部整体偏高,Hg和Pb、Cr和Ni、Zn和Cd元素的空间分布特征较相似.纵向上,As、Cu、Pb、Zn、Cr、Ni等元素含量差异不大,随着深度的增加含量逐渐增加,在黏土层位出现峰值;而Hg和Cd两项元素,则呈现出明显的表聚性.
Geochemistry distribution characteristics and source identification of heavy metals in soil of Fangshan Coal Mine area in Beijing
Fangshan Coal Mine area has a century-long history of coal mining,which may cause pollution to the surrounding ecological environment.In order to evaluate the soil environment condition in Fangshan coal mine area,the most representative mining area was se-lected in Zhoukoudian area of Fangshan as the research area.In the study,196 surface soil samples and 40 deep soil samples were col-lected,and the concentrations of As,Cd,Cr,Hg,Ni,Pb and Zn were tested and analyzed.Using a combination of mathematical statis-tics,cluster analysis,factor analysis,and spatial distribution analysis to study the surface and deep distribution characteristics of heavy metal elements in the soil of Fangshan coal mining area,and explored their sources.The results show that the average values of heavy metal elements in the study area are generally higher than the regional background values in Beijing,with Hg elements being particularly prominent.The distribution of other elements in the surface soil is relatively uniform,except for Hg,Cd,and As.Except for Pb and Zn elements,the enrichment coefficients of other elements in topsoil are generally higher than those in surface soil.Through correlation a-nalysis and cluster analysis,it can be concluded that the sources of Cr and Ni,Hg and Pb,Cd and Zn may be the same.The parent ma-terial and natural soil-forming process may be the main factors affecting the distribution characteristics of Cr and Ni elements in soil,the industrial and mining activities may be the reasons for the high content of Cd and Zn elements,and the geological background combined with human activities may be the reasons affecting the distribution of Hg and Pb elements.From the perspective of spatial distribution the content of heavy metals in the northern part of the study area is higher than that in the southern part,and the spatial distribution characteristics of Hg and Pb,Cr and Ni,Zn and Cd are similar.The contents of As,Cu,Pb,Zn,Cr,Ni and other elements have little difference in the vertical direction,but the contents increase gradually with the increase of depth,and the peak appears in the clay lay-er.However,the two elements Hg and Cd show obvious surface cohesion.

Zhoukoudian Coal Mine areasoil heavy metalsgeochemistrydistribution characteristicsource identification

王秋月、冯辉、杜丽娜

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北京市生态地质研究所,北京 100120

周口店煤矿区 土壤重金属 地球化学 分布特征 来源解析

北京政府公益性项目

PXM2019-158307-000001

2024

能源与环保
河南省煤炭科学研究院有限公司 河南省煤炭学会

能源与环保

CSTPCD
影响因子:0.221
ISSN:1003-0506
年,卷(期):2024.46(2)
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