首页|基于高分子增透剂的煤层注水增渗作用分析

基于高分子增透剂的煤层注水增渗作用分析

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为提高煤体润湿性与注水渗透效果,以自行制备的天然高分子增透剂为基础,从增透剂的反应过程、分子结构微晶结构及其与煤的表面形貌作用效果和润湿作用机理出发,研究了天然高分子增透剂对煤的增渗作用机理,同时利用分子动力学模拟研究了增透剂与煤粉之间的微观作用机理.研究结果表明,添加高分子增透剂后,水对于煤的润湿能力大幅度提升,在相同时间内添加高分子增透剂的试验组呈现出最佳的渗透效果;分子动力学模拟得到增透剂—煤体系的相互作用强度为-232.19 eV,而水—煤体系的相互作用强度为-34.60 eV,表明添加增透剂的溶液体系中水分子更容易附着在煤分子表面上,分子间相互作用力增强,会使附着在煤表面的分子结构更加稳定,更有利于煤表面的润湿.研究结果为煤层注水增透剂的研发和应用提供了参考依据,有助于进一步提高煤层注水抑尘效果.
Analysis of permeability enhancement effect of coal seam water injection based on polymer permeability enhancers
In order to improve the wettability of coal body and water injection permeability effect,on the basis of natural polymer perme-ability enhancer prepared by ourselves,starting from the reaction process,molecular structure,microcrystalline structure,as well as the effect on coal surface morphology and wetting mechanism of natural polymer permeability enhancers,the mechanism of enhancing coal permeability was studied.At the same time,molecular dynamics simulation was used to study the microscopic mechanism of interaction between permeability enhancers and coal powder.The results showed that the wettingability of water to coal was greatly improved after the addition of polymer permeability enhancers,and the experimental group with the addition of polymer permeability enhancer at the same time showed the best permeability effect.Molecular dynamics simulation obtained that the interaction strength between the permea-bility enhancer and coal system was-232.19 eV,while the interaction strength between water and coal system was-34.60 eV,indi-cating that water molecules in the solution system with the addition of permeability enhancer are more likely to adhere to the surface of coal molecules,and the intermolecular interaction force is enhanced,which will make the molecular structure attached to the coal surface more stable and more conducive to the wetting of the coal surface.The research results provide a reference basis for the development and application of coal seam water injection permeability enhancers,which helps to further improve the dust suppression effect of coal seam water injection.

coal seam water injectionpermeability enhancermolecular modificationpenetration mechanismwettability

詹召伟、葛俊岭、徐振、刘涛

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济宁矿业集团有限公司霄云煤矿,山东济宁 272213

济宁市能源局,山东济宁 272213

中煤科工集团重庆研究院有限公司,重庆 400037

煤层注水 增透剂 分子改性 增渗机理 润湿性

重庆市自然科学基金面上项目

cstc2021jcyjmsxmX1184

2024

能源与环保
河南省煤炭科学研究院有限公司 河南省煤炭学会

能源与环保

CSTPCD
影响因子:0.221
ISSN:1003-0506
年,卷(期):2024.46(5)