闽南师范大学学报(自然科学版)2024,Vol.37Issue(4) :28-36.DOI:10.12457/j.issn.2095-7122.2024.04.003

Cs3Cu2Cl5钙钛矿高荧光可视化分辨时间传感防伪膜

Cs3Cu2Cl5 perovskite high fluorescence visual resolution time sensing anti-counterfeiting film

吴曼纯 陈国良 张鹏 李婉婷 陈海妮 李飞明
闽南师范大学学报(自然科学版)2024,Vol.37Issue(4) :28-36.DOI:10.12457/j.issn.2095-7122.2024.04.003

Cs3Cu2Cl5钙钛矿高荧光可视化分辨时间传感防伪膜

Cs3Cu2Cl5 perovskite high fluorescence visual resolution time sensing anti-counterfeiting film

吴曼纯 1陈国良 1张鹏 1李婉婷 1陈海妮 1李飞明1
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作者信息

  • 1. 闽南师范大学化学化工与环境学院,福建 漳州 363000
  • 折叠

摘要

利用传统的热注入方法,引入新型配体双(2,4,4-三甲基戊基)膦酸(TMPPA)制备了Cs3Cu2Cl5NCs纳米晶(nanocrystals,NCs),通过荧光、紫外、X射线衍射(XRD)、扫描电镜(SEM)等表征手段表明成功制备了具有绿色荧光Cs3Cu2Cl5NCs.由于Cs3Cu2Cl5NCs结构中的Cu+在空气中随着时间的推移可以被氧化为Cu2+从而导致其整体结构的坍塌,荧光发生猝灭,因此可以作为设计时间传感模型的良好材料.在实验过程中,通过配体(TMPPA)改性策略调控其粒径大小实现了24 h的时间传感,可为食品安全领域提供了一种新的防伪方式.

Abstract

Cs3Cu2Cl5NCs were prepared by introducing a new ligand,bis(2,4,4-trimethylpentyl)phosphonic acid(TMPPA),using a traditional thermal injection method.Characterization techniques such as fluorescence,ultraviolet,X-ray diffraction(XRD),and scanning electron microscopy(SEM)showed that the NCs with green fluorescence Cs3Cu2Cl5 were successfully prepared.As the Cu+in the Cs3Cu2Cl5NCs structure can be oxidized to Cu2+in the air over time,leading to the collapse of its overall structure and fluorescence quenching,it can be used as a good material for designing time sensing models.During the process of the experiment,the particle size of the ligand(TMPPA)modi-fication strategy was adjusted to achieve 24-hour time sensing,which provides a new anti-counterfeit-ing method for the field of food safety.

关键词

铜基钙钛矿/时间传感/荧光防伪膜/热注入方法

Key words

copper-based perovskite/time sensing/fluorescent security film/thermal injection method

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出版年

2024
闽南师范大学学报(自然科学版)
漳州师范学院

闽南师范大学学报(自然科学版)

影响因子:0.272
ISSN:1008-7826
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