闽南师范大学学报(自然科学版)2024,Vol.37Issue(4) :37-46.DOI:10.12457/j.issn.2095-7122.2024.04.004

燃烧法快速制备CoFe2O4纳米球及其电催化析氢性能

Rapid preparation of CoFe2O4 sphere-like nanomaterial by a rapid combustion method and its electrocatalytic performance for hydrogen evolution

石煜 吴舒琪 邹泽华 高凤 汪庆祥
闽南师范大学学报(自然科学版)2024,Vol.37Issue(4) :37-46.DOI:10.12457/j.issn.2095-7122.2024.04.004

燃烧法快速制备CoFe2O4纳米球及其电催化析氢性能

Rapid preparation of CoFe2O4 sphere-like nanomaterial by a rapid combustion method and its electrocatalytic performance for hydrogen evolution

石煜 1吴舒琪 1邹泽华 1高凤 1汪庆祥1
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作者信息

  • 1. 闽南师范大学化学化工与环境学院,福建 漳州 363000
  • 折叠

摘要

制备兼具稳定性和活性的电解水催化剂是大规模制氢的关键环节.通过快速燃烧法,在双金属泡沫镍铜(NCF)表面原位合成了CoFe2O4纳米球.通过 X 射线衍射(XRD)和扫描电子显微镜(SEM)对材料的结构和组成进行了表征.采用线性扫描伏安法(LSV)考察了该材料在碱性环境下对电解水析氢反应(HER)的催化性能.结果显示,析氢反应达到10 mA×cm-2电流密度所需的过电位仅为 148 mV,Tafel 斜率为 197 mV×dec-1,明显优于裸NCF和单金属对照材料.稳定性测试实验表明,经过 2 000 次循环伏安扫描后,析氢反应LSV曲线与与原始曲线基本一致;同时在100 mA×cm-2 的电流密度持续电解25 h,电位不发生明显变化,表明该催化剂具有良好的电催化稳定性.

Abstract

The preparation of catalysts that possess both high stability and activity for electrolysis of water is a key step for the large-scale hydrogen production.Herein,the CoFe2O4 nanospheres were in-situ synthesized on the surface of the bimetallic nickel-copper foam(NCF).The structure and compo-sition of the material were characterized by X-ray diffraction(XRD)and scanning electron micro-scope(SEM).The catalytic performance of the material for the hydrogen evolution reaction(HER)in an alkaline environment was investigated using linear sweep voltammetry(LSV).The results show that the overpotential required for the HER to reach a current density of 10 mA×cm-2 is only 148 mV with a Tafel slope of 197 mV×dec-1.significantly outperforming bare NCF and single-metal control materials.Stability tests indicate that after 2 000 cycles of cyclic voltammetry scans,the LSV curve for the HER is essentially consistent with the original curve.Simultaneously,under a continu-ous electrolysis at a current density of 100 mA×cm-2 for 25 hours,the potential does not change signifi-cantly,indicating that the catalyst possesses good electrocatalytic stability.

关键词

泡沫镍铜/CoFe2O4/快速燃烧法/电催化/析氢反应

Key words

nickel-copper foam/CoFe2O4/rapid combustion method/electrocatalysis/hydrogen evo-lution reaction

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出版年

2024
闽南师范大学学报(自然科学版)
漳州师范学院

闽南师范大学学报(自然科学版)

影响因子:0.272
ISSN:1008-7826
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