Tetrahedron letters2022，Vol.975.DOI:10.1016/j.tetlet.2022.153799

Palladium-catalyzed stereo-selective three-component cis-1,2-arylalkynylation of bicyclic alkenes with aryltriflates and terminal alkynes

Xu, Tianhao Zhou, Xiangbing Han, Yuhui Zhang, Liangwei Liu, Long Huang, Tianzeng Li, Chunya Tang, Zhi Wan, Shungang Chen, Tieqiao
Tetrahedron letters2022，Vol.975.DOI:10.1016/j.tetlet.2022.153799
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  • NSTL
  • Elsevier

Palladium-catalyzed stereo-selective three-component cis-1,2-arylalkynylation of bicyclic alkenes with aryltriflates and terminal alkynes

Xu, Tianhao 1Zhou, Xiangbing 1Han, Yuhui 1Zhang, Liangwei 1Liu, Long 1Huang, Tianzeng 1Li, Chunya 1Tang, Zhi 1Wan, Shungang 1Chen, Tieqiao1
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作者信息

  • 1. Hainan Univ
  • 折叠

Abstract

A palladium-catalyzed stereo-selective cis-1,2-arylalkynylation of bicyclic alkenes with aryl triflates and terminal alkynes was developed. This reaction showed high functional group tolerance and can be applied to the modification of bioactive molecules. This three-component reaction provided a practical method for preparing the value-added bicyclo[2.2.1]heptanes derivatives. (c) 2022 Elsevier Ltd. All rights reserved.

Key words

Palladium catalysis/Bicyclic alkenes/Phenol derivatives/Difunctionalization/CROSS-COUPLING REACTIONS/ARYL IODIDES/NORBORNADIENE/ACTIVATION/DERIVATIVES/COMPLEXES/CLEAVAGE/DIFUNCTIONALIZATION/FUNCTIONALIZATION/CARBOACYLATION

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出版年

2022
Tetrahedron letters

Tetrahedron letters

CCR
ISSN：0040-4039
被引量1
参考文献量66
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