首页|Effect of oxygen impurity on long-term thermal stability of Zr-based metallic glasses below glass transition temperature

Effect of oxygen impurity on long-term thermal stability of Zr-based metallic glasses below glass transition temperature

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Long-term thermal stability of a series of Zr-based metallic glasses with different oxygen contents below their glass transition temperatures was compared based on their deductive continuous-heating-transformation diagrams created by using the corollary of Kissinger analysis method. It is found that the influence of oxygen on the long-term thermal stability of Zr-based metallic glasses exhibits at lower temperature is different from that on their short-term thermal stability presented at higher temperature. For each kind of the Zr-based metallic glasses, there is a critical heating rate, PHI_c, which corresponds to a critical temperature, T_c. As heating rate is smaller than PHI_c and onset devitrification temperature is below T_c, the glass with higher oxygen content will have longer incubation period for onset devitrification. The values of PHI_c and T_c are related with the glasses' reduced glass transition temperature T_(rg) The improving effect of oxygen impurity on the long-term thermal stability of Zr-based metallic glasses was discovered.

Zr-based metallic glassesthermal stabilitycontinuous heating transformation diagramoxygen impurity

HE Lin、ZHANG Shuai、SUN Jun

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State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China

2006

Transactions of Nonferrous Metals Society of China

Transactions of Nonferrous Metals Society of China

ISTP
ISSN:1003-6326
年,卷(期):2006.16(5)