首页|A novel heterogeneous reaction for generating gaseous nitrous acid
A novel heterogeneous reaction for generating gaseous nitrous acid
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The short-lived reactive specimen nitrous acid HONO was generated in the gas phase by the heterogeneous reaction of gaseous HCI with AgNO_2 which can generate higher concentration of HONO than other methods. We investigated the process from generation to dissociation in the gas phase under different controlled temperatures, and discussed the ionization and reaction on the solid surface by combination of the photoelectron spectroscopy and photoionization mass spectroscopy (PES-PIMS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).
HONOPES-PIMSDRIFTS
WANG WeiGang、GE MaoFa、YAO Li、ZENG XiaoQing、WANG ZiFa
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Beijing National Laboratory for Molecular Sciences, and State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
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