首页|Synthesis of Nano-sized Oxide Phosphor Particles Using an Ion-exchange Polymer/Water/Oil Emulsion Method

Synthesis of Nano-sized Oxide Phosphor Particles Using an Ion-exchange Polymer/Water/Oil Emulsion Method

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We synthesized nano-sized Eu-doped Y_2O_3 (Y_2O_3:Eu) phosphor powder by an ion-exchange polymer/water/oil (W/O) emulsion method using carboxymethyl cellulose (CMC) as the ion-exchange polymer, in which the CMC-(Y, Eu) gel formed was calcined at 800℃ in air to convert into Y_2O_3:Eu particles. The obtained phosphor powder consists of unagglomerated particles with sizes in the range of 30-80 nm and exhibits strong red emission at 612 nm. This CMC/W/O method for producing nano-sized oxide powder has significant advantages over conventional solid-phase and chemical solution-based methods because this method can provide unagglomerated nanoparticles of oxide phosphor without employing any mechanical pulverizing process for reducing the particles' size into the nanometer range; mechanical grinding, such as ball milling, of phosphor powders has been well known to cause a significant degradation of their luminescent properties.

nano-sized oxide phosphorY_2O_3:EucarboxymethylcelluloseW/O emulsion

Hiroyuki Sano、Seiichirou Harada、Mikio Shimizu、Makoto Kuwabara

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Department of Applied Science for Electronics and Materials, Kyushu University, 6-1 Kasuga-kouen, Kasuga, Fukuoka 816-8580, JAPAN

2010

Key engineering materials

Key engineering materials

ISSN:1013-9826
年,卷(期):2010.421/422
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