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Ionic conductivity induced loss of birefringence of banana-shaped liquid crystal
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NETL
NSTL
Trans Tech Publications Ltd
The effects of ionic conductivity on the electro-optical properties of a chiral banana-shaped liquid crystal 1,3-phenylene bis{4-[3-chloro-4-(3,7-dimethyloctyloxyl)] phenyliminomethyl} benzoate were investigated with the techniques of polarizing optical microscopy and dielectric spectroscopy. When the banana-shaped liquid crystal was experienced a low-frequency (1 Hz) triangular waveform electric field, its polarizing optical microscopic textures were first turned into gray and then into black at about 95℃, a few degrees lower than the clearing temperature of the banana-shaped liquid crystal. Detailed dielectric spectroscopic characterizations showed that ionic conductivity increased exponentially as the temperature increased from 72 to 110℃. Our results suggested that dominant ionic conductivity near its clearing temperature is responsible for the electric-field induced loss in the birefringence of the banana-shaped liquid crystal.