首页|Mesomorphic properties of three-benzene-ring containing bent-core liquid crystals 1,3-phenylene-bis[4-(alkylcarboyloxyl)benzylideneamine]
Mesomorphic properties of three-benzene-ring containing bent-core liquid crystals 1,3-phenylene-bis[4-(alkylcarboyloxyl)benzylideneamine]
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NSTL
Trans Tech Publications Ltd
A homologous series of three-benzene-ring containing bent-cores compounds 1,3-phenylene-bis[4-(alkylcarboyloxyl)benzylideneamine] were synthesized. In these molecules the terminal ester chains CH_3(CH_2)_(n-2)COO-, where n was the number of carbon atoms in the terminal chains, were linked to the central three-benzene-ring containing bent-core. As n changed from 1-12, the melting temperatures and clearing points were in the high temperature ranges of 136-206℃. As n changed in the range of 14-19, the melting temperatures and clearing points were dramatically dropped in a low temperature ranges 60-82℃.