首页|Synthesis and mesogenic properties of a novel hyperbranched triphenylene-based discotic liquid crystal

Synthesis and mesogenic properties of a novel hyperbranched triphenylene-based discotic liquid crystal

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A novel triphenylene-based hyper-branched macromolecule was synthesized from the functional compoimd-2,6,10-trihydroxy-3, 7, 11-tris (pentyloxy) triphenylene serving as core, using α,ω-dibromodecane as spacer and 1 -bromopentane as terminal group for end capping by using a very simple synthesis method, one-pot reaction. The structure of the hyperbranched macromolecule was determined by FTIR and 1HNMR. The molecule weight and the molecular weight distribution were measured by GPC. Mesophase and their structural orders were determined using a polarized optical microscope and a differential scanning calorimeter.

discotic liquid crystaltriphenylenecolumnar phasehyperbranched

Chunxiu Zhang、Jialing Pu、Zhiqun He、Ming Zhang、Hao Wu、Yanan Li

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Information Recording Materials Lab, Beijing Institute of Graphic Communication, Beijing102600, PR China Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, PR China

Information Recording Materials Lab, Beijing Institute of Graphic Communication, Beijing102600, PR China

Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, PR China

2010

Key engineering materials

Key engineering materials

ISSN:1013-9826
年,卷(期):2010.428/429
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