首页|Effect of Hexagonal BN on the Microstructure and Mechanical Properties of Pressureless Sintered Porous Si_3N_4 Ceramics
Effect of Hexagonal BN on the Microstructure and Mechanical Properties of Pressureless Sintered Porous Si_3N_4 Ceramics
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NETL
NSTL
Trans Tech Publications Ltd
Porous silicon nitride ceramics with various amounts (25, 35, and 45 vol %) of hexagonal boron nitride (h-BN) were fabricated at 1800℃ for 2h by the pressureless sintering process. With FESEM and TEM, the effects of h-BN on the microstructure and mechanical properties of Si_3N_4 ceramics were investigated. Results of the microstructure and mechanical properties of Si_3N_4/BN composites showed that the growth of the elongated β-Si_3N_4 were hindered by h-BN additive, which resulted in the decrease of fracture toughness of Si_3N_4/BN ceramics with increasing h-BN content. The morphologies of the fracture surfaces by FESEM revealed the fracture mode for Si_3N_4/BN composites to be intergranular. However, phase analysis by XRD indicated that the effect of h-BN on the α- to β-Si_3N_4 phase transformation of Si_3N_4/BN composites was negligible.