Journal of Alloys and Compounds2022,Vol.90614.DOI:10.1016/j.jallcom.2022.164255

Synergistic S-Scheme mechanism insights of g-C3N4 and rGO combined ZnO-Ag heterostructure nanocomposite for efficient photocatalytic and anticancer activities

Vignesh S. Srinivasan M. Venkatesh G. Elavarasan N. Palanisamy G. Ramasamy P. Palanivel B. Al-Enizi A.M. Ubaidullah M. Minnam Reddy V.R. Kim W.K.
Journal of Alloys and Compounds2022,Vol.90614.DOI:10.1016/j.jallcom.2022.164255

Synergistic S-Scheme mechanism insights of g-C3N4 and rGO combined ZnO-Ag heterostructure nanocomposite for efficient photocatalytic and anticancer activities

Vignesh S. 1Srinivasan M. 1Venkatesh G. 1Elavarasan N. 1Palanisamy G. 1Ramasamy P. 1Palanivel B. 2Al-Enizi A.M. 3Ubaidullah M. 3Minnam Reddy V.R. 4Kim W.K.4
扫码查看

作者信息

  • 1. SSN Research Centre Sri Sivasubramaniya Nadar College of Engineering
  • 2. Department of Physics Kings Engineering College
  • 3. Department of Chemistry College of Science King Saud University
  • 4. School of Chemical Engineering Yeungnam University
  • 折叠

Abstract

? 2022 Elsevier B.V.The g-C3N4/rGO/ZnO-Ag (GCRZA) composite photocatalyst (PC) prepared by the facile hydrothermal method was effectively studied. The structural, morphological and optical, properties of as-synthesized materials were characterized by various characterization techniques. Photocatalytic activity of the as-prepared composite was examined using rhodamine B and methylene blue mixed (RhB+MB) aqueous dye under UV–visible light irradiation for 100 min. The GCRZA composite displayed a better photocatalytic performance against MB dye (90.04%) and RhB dye (83.45%) degradation performance. Moreover, the GCRZA composite PCs exhibited higher photocatalytic activity than pristine g-C3N4. The ultimate photocatalytic property was attained by implementating of g-C3N4/rGO in ZnO-Ag heterostructure, which could effectively decrease the optical bandgap and high visible-light absorption ability with suppressed e?/h+ recombination rate. After the five consecutive photocatalytic recycles, the GCRZA composite PC showed good stability without structural changes. Furthermore, the IC50 values showed that GCRZA nanocomposite (NC) has a higher cytotoxicity effect than g-C3N4/ZnO-Ag, g-C3N4/rGO and g-C3N4 against both HeLa and MCF-7 cell lines. As a result, this combination of nanocomposite has proven to exhibit higher photocatalytic and anticancer activity. Eventually, it may prove to be an effective tool for eradicating dye pollution from wastewater, and a way to prevent cancer mediated diseases in the cosmetics and pharmaceutical industries.

Key words

Anticancer/G-C3N4/rGO/ZnO-Ag/Mixed dye degradation/Nanocomposite/Photocatalysts

引用本文复制引用

出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量27
参考文献量67
段落导航相关论文