首页|Neutron vibrational spectroscopic evidence for short H center dot center dot center dot H contacts in the RNiInH1.4; (1.6) (R = Ce, La) metal hydride
Neutron vibrational spectroscopic evidence for short H center dot center dot center dot H contacts in the RNiInH1.4; (1.6) (R = Ce, La) metal hydride
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Elsevier
Intermetallic metal hydrides are critical materials for hydrogen storage applications, however, metal hydrides with greater storage capacities are still needed. Within metal hydrides, the volumetric storage capacities are limited by the number of hydrogen-accommodating interstitial sites which can be simultaneously occupied given a minimum hydride nearest-neighbor distance of approximate to 2.1 angstrom, according to the Switendick-Westlake criterion. To date, violations of this criterion are rare. Perhaps the most well studied compounds violating this criterion are the RNiInHx compounds (R = Ce, La, Nd). Previous neutron diffraction studies on the deuterated species revealed the presence of Ni-D center dot center dot center dot D-Ni-D center dot center dot center dot D-Ni chains with anomalously close D center dot center dot center dot D contacts of approximate to 1.6 angstrom. Yet there are no neutron vibrational spectroscopic investigations reported for these atypical hydrides. Here we use neutron vibrational spectroscopy (NVS) measurements to probe the hydrogen dynamics in LaNiInHx (x = 0.67, 1.6) and CeNiInH1.4. For x > 0.67, the presence of close H center dot center dot center dot H contacts yields two related features in the vibrational spectrum centered near approximate to 90 meV corresponding to the oscillations of paired H atoms simultaneously occupying neighboring R3Ni tetrahedra. Notably, these features are energetically distinct from comparable vibrational motions for "unpaired" H atoms when x <= 0.67. To compare, we also present powder neutron diffraction and NVS measurements for the newly characterized, chemically similar Sn compounds CeNiSnH, CeNiSnH2, and CeNiSnD2. These compounds also contain R3Ni tetrahedra, however, the H-occupied tetrahedra are well separated from each other with the closest H center dot center dot center dot H distances exceeding 2.1 angstrom, and the Switendick-Westlake criterion is not violated. Consequently, the spectral signature of the close H center dot center dot center dot H contacts is absent in these hydrides. Published by Elsevier B.V.
NSTL
Elsevier
