首页|High temperature thermophysical properties of spark plasma sintered tungsten carbide

High temperature thermophysical properties of spark plasma sintered tungsten carbide

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? 2022 Elsevier LtdFast Breeder Test Reactor (FBTR) is a unique Indian fast reactor and irradiation facility for materials testing. As a part of its life extension activities, high density tungsten mono carbide (α-WC) is considered as a candidate material for the lower axial neutron shielding of the grid plate. Spark plasma sintering technique is used to synthesize high density (99.5%) tungsten carbide pellets under optimized conditions without a binder phase and subjected to high temperature thermal property characterization. The dilatational strain, thermal diffusivity as well as the resonance frequency of flexural vibration is measured as a function of temperature and the corresponding values of linear thermal expansion, thermal conductivity and the dynamic Young's modulus are estimated. The measured values are analyzed in combination with quasi-harmonic Debye-Grüneisen model to obtain a comprehensive database on vibrational thermodynamic properties from 0 to 1273 K. The observed Debye temperature for tungsten carbide under ambient conditions is 630 K which gradually decreases to 586 K at 1273 K. The estimated thermal Grüneisen parameter varied in the range of 1.41–1.45.

Dynamic elastic moduliQuasi harmonic modelSpark plasma sinteringThermophysical propertiesTungsten carbide

Tripathy H.、Sudha C.、Paul V.T.、Thirumurugesan R.、Prasanthi T.N.、Sundar R.、Vijayashanthi N.、Parameswaran P.、Raju S.

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Physical Metallurgy Division Indira Gandhi Centre for Atomic Research

Metallurgy and Materials Group Indira Gandhi Centre for Atomic Research

2022

International Journal of Refractory Metals & Hard Materials

International Journal of Refractory Metals & Hard Materials

SCI
ISSN:0263-4368
年,卷(期):2022.104
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