Journal of Alloys and Compounds2022,Vol.9059.DOI:10.1016/j.jallcom.2022.164025

ZnO@Ti3C2 MXene interfacial Schottky junction for boosting spatial charge separation in photocatalytic degradation

Li J. Bian R. Ji Y. Tian J. Wang X. Shi F. Cui H. Zhang X. Liu M.
Journal of Alloys and Compounds2022,Vol.9059.DOI:10.1016/j.jallcom.2022.164025

ZnO@Ti3C2 MXene interfacial Schottky junction for boosting spatial charge separation in photocatalytic degradation

Li J. 1Bian R. 1Ji Y. 1Tian J. 1Wang X. 1Shi F. 1Cui H. 1Zhang X. 2Liu M.1
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作者信息

  • 1. School of Materials Science and Engineering Shandong University of Science and Technology
  • 2. School of Materials Science and Engineering Zhengzhou University
  • 折叠

Abstract

? 2022 Elsevier B.V.Herein, we report a ZnO@Ti3C2 MXene composite obtained using a simple hydrothermal method for increasing the photocatalytic degradation ability of methylene blue (MB). When the addition amount of Ti3C2 MXene is 50%, the ZnO@Ti3C2 MXene composite exhibited the best photocatalytic degradation performance (94.84%), and the reaction rate constant is 0.01223 min?1, which is 47 and 30 times of pure ZnO (5.59%, 0.026 ×10–2 min?1) and pure Ti3C2 MXene (7.56%, 0.04050 ×10–2 min?1), respectively. Moreover, the ZnO@Ti3C2 MXene composite exhibited good stability. The photocatalytic mechanism of ZnO@Ti3C2 MXene composite is proposed. The addition of Ti3C2 MXene forms a Schottky junction between ZnO and Ti3C2 MXene. The Schottky junction prevents the photogenerated electrons from returning to ZnO and promotes the separation of photogenerated electrons and holes, thus effectively improving the photocatalytic performance of ZnO@Ti3C2 MXene composite.

Key words

Photocatalytic degradation/Schottky junction/Ti3C2 MXene/ZnO

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量44
参考文献量30
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