首页|Microstructure and electrical properties of new high-entropy rare-earth zirconates
Microstructure and electrical properties of new high-entropy rare-earth zirconates
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NSTL
Elsevier
? 2022 Elsevier B.V.In the present work, a series of new high-entropy rare-earth zirconates were prepared by a solid state reaction method. The crystal structure, microstructure and electrical properties of high-entropy rare-earth zirconates were characterized by means of X-ray diffraction, Raman spectroscopy, scanning electron microscopy, transmission electron microscopy and electrochemical impedance spectroscopy. All the high-entropy rare-earth zirconates have a single-phase pyrochlore structure with a relative density of more than 95.7%. The grain sizes of high-entropy rare-earth zirconates are 1.3–2.4 μm, which are finer than low-entropy rare-earth zirconates prepared by the same process. (Nd0.2Sm0.2Eu0.2Gd0.2Dy0.2)2Zr2O7 has the excellent electrical conductivity of 7.1 × 10–3 S·cm–1 at 1073 K.
Wang Y.、Ding Z.-Y.、Cao G.、Liu Z.-G.、Jin Y.-J.、Ouyang J.-H.、Wang Y.-M.、Wang Y.-J.、Wei T.
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Key Laboratory of Advanced Structural-Functional Integration Materials & Green Manufacturing Technology School of Materials Science and Engineering Harbin Institute of Technology
Nuclear Fuel Cycle Research Theme Australian Nuclear Science and Technology Organisation
NSTL
Elsevier
