首页|Influence of acceptor–donor codoping on the structure, electrical properties, and hardness of CaBi2Nb2O9-based ceramics

Influence of acceptor–donor codoping on the structure, electrical properties, and hardness of CaBi2Nb2O9-based ceramics

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? 2022 Elsevier B.V.An appropriate amount of (Li,Ce) ions are incorporated into bismuth layer-structured piezoelectric ceramics to reduce the oxygen vacancy concentration, limit the grain growth, and enhance the electrical properties and hardness of the ceramics. The existence of a pseudo-tetragonal phase region, the change in the domain structure, and the increase in the spontaneous polarization promote the enhancement of the piezoelectric properties. Additionally, the conductive mechanism in the high-temperature regions is discussed in terms of the direct-current resistivity. A moderate amount of the (Li,Ce) dopant ions can effectively improve the thermal depoling behavior of CaBi2Nb2O9 (CBN)-based ceramics. Consequently, the Ca0.88(LiCe)0.06Bi2Nb2O9 ceramic exhibits an optimal d33 piezoelectric coefficient of 18.5 pC/N and an excellent thermal depoling behavior. Furthermore, the results of the Vickers indentation hardness test reveal that the hardness of CBN-based ceramics is improved to 3.78 GPa.

Bismuth layer-structured ferroelectrics materialsCaBi2Nb2O9Domain structureVickers hardness

Xing J.、Chen Q.、Zhu J.、Xu Q.、Wang F.、Li X.、Chen N.、Chen H.、Cheng Y.、Zhang F.、Tan Z.

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College of Materials Science and Engineering Sichuan University

Key Laboratory of Deep Underground Science and Engineering (Ministry of Education) College of Architecture and Environment Sichuan University

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.910
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