A BODIPY decorated multiple mode reusable paper-based colorimetric and fluorometric pH sensor
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In this study,two difluoroboradiazaindacene(BODIPY)compounds bearing diethylaminostyryl groups were synthesized in order to establish colorimetric and fluorometric paper-based pH sensors.The structures of these novel BODIPY compounds were identified by NMR(1H,~(13)C,~(11)B,and ~(19)F),elemental analysis,MALDI-TOF,FT-IR,UV-vis and fluorescence spectroscopies as well as single-crystal X-Ray data.The DFT study was also performed to optimize of these two novel BODIPY structures.Electrochemical measurements were applied to estimate their redox potentials.Photophysical properties such as fluorescence quantum yield and lifetimes were investigated to determine the effect of acid addition in both DMSO and 1,4-dioxane solutions of the studied BODIPY derivatives.Also,pKa values of the synthesized compounds(la and lb)were determined from absorbance and fluorescence measurements by acid titration studies.The paper-based pH sensor behavior of these BODIPY derivatives was investigated and their performances were determined on the lemon juice samples as a real sample analysis.A simple,cost-effective,rapid,portable,colorimetric,and fluorometric paper-based BODIPY sensing platform was developed in this study for the detection of the variety of pH changes in lemon juice.
BODIPYpH sensorNaked-eyePaper-based
Baybars Koksoy、Dilek Oztiirk、Ipek Omeroglu
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Bursa Technical University,Department of Chemistry,16310,Bursa,Turkey
Gebze Technical University,Department of Chemistry,41400,Gebze,Kocaeli,Turkey
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