首页|Direct single-step synthesis of phase pure zeolite Na-P1, hydroxy sodalite and analcime from coal fly ash and assessment of their Cs+ and Sr2+ removal efficiencies
Direct single-step synthesis of phase pure zeolite Na-P1, hydroxy sodalite and analcime from coal fly ash and assessment of their Cs+ and Sr2+ removal efficiencies
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NSTL
Elsevier
Combustion by-products of coal from thermal power plants cause environmental pollution; efforts are made to develop techniques and green processes that could reduce the waste volume and convert the waste to useful materials. Synthesis of phase pure zeolites from coal fly ash and its use as adsorbent and ion exchangers to remove Cs+ and Sr2+ from simulated nuclear waste solutions is the focus of the current study. Zeolite Na-P1, hydroxy sodalite and analcime were synthesized from fly ash obtained from an Indian thermal power plant by using hydrothermal method. Zeolite synthesis conditions were optimized by studying the effect of concentration of NaOH solution, homogenization time, hydrothermal temperature and time. The zeolite phase formation, surface morphology, thermal stability studies were carried out by XRD, SEM, TG-DTA techniques; specific surface area was determined by BET analysis. Crystalline pristine zeolite Na-P1 was prepared from fly ash on reaction with 1 M NaOH at 150 degrees C. Similarly, hydroxy sodalite and analcime were also synthesized from the fly ash by hydrothermal reaction with 3 M NaOH at 150 degrees C and 5 M NaOH at 200 degrees C respectively. The removal efficiencies of synthesized zeolites were investigated with aqueous simulated nuclear waste solutions containing Cs+ and Sr2+. The adsorption capacities and cation exchange capacity (CEC) of zeolite Na-P1, hydroxy sodalite and analcime for Cs+ and Sr2+ ions were demonstrated. The results show the adsorption capacity of Na-P1 for Cs+ is 39.3 mg/g and for Sr2+ is 92.48 mg/g respectively and is a better adsorbent than analcime and hydroxy sodalite.
NSTL
Elsevier
