首页|Influence of organically modified nanoclay and TiO(2)nanopowder on the properties ofAzadirachta indicawood flour-reinforced high-density polyethylene, low-density polyethylene, polypropylene, and polyvinyl chloride nanocomposite

Influence of organically modified nanoclay and TiO(2)nanopowder on the properties ofAzadirachta indicawood flour-reinforced high-density polyethylene, low-density polyethylene, polypropylene, and polyvinyl chloride nanocomposite

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The nanocomposites of high-density polyethylene, low-density polyethylene, polypropylene, and poly(vinyl chloride) reinforced withAzadirachta indicawood flour (WF) and different amounts of the organomodified nanoclay and titanium dioxide (TiO2) nanopowder were produced by melt-blending process followed by compression molding. Polyethylene-co-glycidyl methacrylate (PE-co-GMA) was used as a compatibilizer. TiO(2)nanopowder was synthesized by sol-gel method and characterized using transmission electron microscopy (TEM). The average size of the synthesized nano-TiO(2)was 17.5 nm, which was confirmed both by TEM and X-ray diffraction (XRD) study. The distribution of nanoparticles in the nanocomposites was also examined by the XRD study. The surface modification of the TiO(2)nanoparticles by organic surfactant cetyl trimethyl ammonium bromide and their interaction with the wood and the polymer were studied by Fourier transform infrared spectroscopy. Incorporation of compatibilizer PE-co-GMA, nanoclay, and nano-TiO(2)significantly influenced the mechanical and thermal properties of the WF-reinforced composites. Wood polymer composites (WPC) reinforced with nanoclay and nano-TiO(2)showed improved tensile strength, tensile modulus, flexural strength, flexural modulus, and hardness. Maximum improvement in mechanical properties was shown by WPC loaded with 40 phr WF, 2 phr nanoclay, and 2 phr of nano-TiO2. On inclusion of organically modified nanoclay and nano-TiO2, the WPC samples showed lower water uptake and higher chemical resistance. The nanocomposites were further examined by TEM study and thermogravimetric analyzer.

Wood fiberthermoplasticsnanocompositemechanical propertiesnanofillerMECHANICAL-PROPERTIESTHERMAL-PROPERTIESPHYSICAL-PROPERTIESVISIBLE-LIGHTWOODCOMPOSITESFIBERTIO2TITANIAFLAMMABILITY

Maji, Tarun K.、Devi, Nirmala、Rathnam, Vamsi、Kichu, Arenjungla、Dutta, Nipu

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Tezpur Univ

Natl Inst Technol Nagaland

2022

Journal of Thermoplastic Composite Materials

Journal of Thermoplastic Composite Materials

EISCI
ISSN:0892-7057
年,卷(期):2022.35(Oct.)
  • 6
  • 66