首页|Design and synthesis of single phase Hf0.25Zr0.25Ce0.25Y0.125Si0.125O2-δ high-entropy ceramics

Design and synthesis of single phase Hf0.25Zr0.25Ce0.25Y0.125Si0.125O2-δ high-entropy ceramics

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? 2022 Elsevier B.V.We design and synthesise a new high-entropy ceramic Hf0.25Zr0.25Ce0.25Y0.125Si0.125O2-δ through a hybrid mixing of non-metal and metal atoms. First-principles calculations predict the thermal stability of the single-crystal phase at high temperatures. XRD and EDS mapping confirm a single cubic fluorite phase with a uniform elemental distribution. In-situ high-temperature XRD shows that the phase is stable with no phase separation or secondary phases. The measured mechanical and thermal properties are comparable with reported high-entropy fluorite oxides. Our results add to the compositional space of high-entropy ceramics for a wide range of applications from thermal insulators to electronics.

High-entropy ceramicsHybrid mixingMechanical propertiesThermal properties

Lim P.C.、Liew S.L.、Zhou J.、Wei F.、Ni X.P.、Tan S.Y.、Lee J.J.C.、Wang S.、Yang M.、Luai M.T.

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Institute of Materials Research & Engineering A?STAR (Agency for Science Technology and Research)

Department of Applied Physics The Hong Kong Polytechnic University

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.904
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