首页|(???????)Synergistic effects of tungsten coating on the microstructure, thermophysical and mechanical properties of graphite flakes reinforced copper matrix composites
(???????)Synergistic effects of tungsten coating on the microstructure, thermophysical and mechanical properties of graphite flakes reinforced copper matrix composites
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NSTL
Elsevier
With the rapid development of the miniaturization and high-integration of electronic devices, conventional thermal conductive materials cannot ensure the safety and reliability of the high-power devices in working environments. It is urgent to develop thermal management materials with excellent thermo-physical and mechanical properties. In this work, the tungsten-coated graphite flakes (GFs(W)) were prepared by the immersion reduction, and the GFs(W) reinforced copper matrix composites (GFs(W)/Cu composites) were prepared by the vacuum hot-pressing sintering. Based on the microstructure and surface analysis, the W coating obtained at 900 & DEG;C and 200 g/L AMT appears the excellent surface structure and interfacial adhesion, which transfer the interfacial bonding from mechanical combination to mechanical-metallurgical synergy between the GFs and Cu. In addition, the volume fraction of W coating has a threshold to improve properties of the GFs(W)/Cu composites, in which the GFs(6 W)/Cu composites show the outstanding comprehensive performance: the in-plane thermal conductivity and flexural strength are 879.0 & PLUSMN; 10.0 Wm(-1)K(-1) and 166.9 & PLUSMN; 3.4 MPa respectively, which are improved by 22.3% and 356.0%, and the lowest coefficient of thermal expansion is 4.3 & PLUSMN; 0.5 ppmK(-1). To sum up, it provides an effective way to develop novel structural and functional integrated graphite/copper composites for thermal management. (c) 2022 Published by Elsevier B.V.