首页|Highly efficient blue all-solution-processed organic light-emitting diodes based on the strategy of constructing a thermally cross-linkable TADF dendrimer

Highly efficient blue all-solution-processed organic light-emitting diodes based on the strategy of constructing a thermally cross-linkable TADF dendrimer

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Based on the strategy of constructing a new cross-linkable thermally activated delayed fluorescence TADF dendrimer act as the emitter, the blue all-solution-processed organic light-emitting diodes (OLEDs) was developed. Here, two thermally cross-linkable TADF molecules, namely DV-3CzCN and DVCz-3CzCN, are designed and synthesized. Systematic studies demonstrate that the utilization of DVCz-3CzCN can form a stable and uniform thin film by the solution-process, but also effectively suppress the triplet excitons concentration quenching by the intermolecular interaction. Simultaneously, DVCz-3CzCN possesses the sufficient solvent resistance that can afford the subsequently deposition of electron transporting materials by orthogonal solvent. Consequently, the highly efficient blue all-solution-processed device based on DVCz-3CzCN realized a maximum current efficiency (CE), power efficiency (PE) and external quantum efficiency (EQE) of 7.1 cd A(-1), 4.5 lm W-1 and 6.8%, respectively, which is eight times higher in device efficiency than corresponding device with the unencapsulated DV-3CzCN.

TADFDendrimerCross-linkableAll-solution-processedOLEDsACTIVATED DELAYED-FLUORESCENCEPOLYMERSCOPOLYMERSBACKBONEEMITTERSDESIGNGREENOLEDSHOSTS

Sun, Kaiyong、Wu, Jie、Zhu, Lingling、Liu, Hongxiang、Zhou, Yu、Tian, Wenwen、Cai, Zhaosheng、Jiang, Wei、Sun, Yueming

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Yancheng Inst Technol

Southeast Univ

2022

Dyes and Pigments

Dyes and Pigments

EISCI
ISSN:0143-7208
年,卷(期):2022.198
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