Unsaturated,Mixed-Valence Diiron Dithiolate Model for the H

Unsaturated,Mixed-Valence Diiron Dithiolate Model for the H_(ox)State of the[FeFe]Hydrogenase

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外文摘要：The[FeFe]hydrogenase enzymes are the most efficient catalysts known for the reduction of protons to H2.The active site exists in two functional states(Scheme 1),H_(red),which is S=0,and H_(ox),which is S=l/2.Research in this area is aimed at elucidating the mechanism of the enzymatic catalysis and at using this information to develop protein-free bioinspired synthetic catalysts.

外文关键词：

hydrogenhydrogenasesironmixed-valent compoundsthiolates

作者：

Aaron K.Justice、Thomas B.Rauchfuss、Scott R.Wilson

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作者单位：

Department of Chemistry University of Illinois at Urbana-Champaign 600 South Mathews Ave.,Urbana,IL 61801(USA)

出版年：

2007

Angewandte Chemie

ISSN：1433-7851

年,卷(期)：2007.46(32)