首页|Effect of heavy rare-earth (Dy, Tb, Gd) addition on the glass-forming ability and magneto-caloric properties of Fe89Zr7B4 amorphous alloy

Effect of heavy rare-earth (Dy, Tb, Gd) addition on the glass-forming ability and magneto-caloric properties of Fe89Zr7B4 amorphous alloy

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? 2022 Elsevier B.V.In this paper, by adding rare-earth (RE) elements to Fe89Zr7B4 ternary amorphous alloy, we obtained a series of Fe87Zr7B4RE2 (RE = Dy, Tb, Gd) amorphous ribbons to further improve the magnetic refrigeration capacity of the basic alloy. Through the heavy RE element substitutions, the glass-formability of the Fe89Zr7B4 alloy was improved effectively. Besides, the Curie temperature Tc of the alloy system increased from 275 K to 342 K, obtaining a roughly linear correlation between the de Gennes factor and Tc. Through the recombination of ribbons with different Tc values, we designed potential amorphous composites with a “table-like” magnetic entropy change curve under different temperatures. This research promises to deepen understanding of the effect of RE additions on the magneto-caloric properties and enhance the performance of Fe-Zr-B amorphous refrigerants around room temperature.

Amorphous alloyGlass-forming abilityMagnetic entropy changeMagneto-caloric effect

Xia L.、Peng J.、Tang B.、Bai C.、Wu Y.、Chen Q.、Li D.、Guo X.、Yu P.、Wang Q.、Ding D.

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Institute of Materials & Laboratory for Microstructure Shanghai University

College of Physics and Electronic Engineering of Chongqing Normal University Chongqing Key Laboratory of Optical and Electronic Functional Materials

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.925
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