首页|Self-powered TiO2 NRs UV photodetectors: Heterojunction with PTTh and enhanced responsivity by Au nanoparticles

Self-powered TiO2 NRs UV photodetectors: Heterojunction with PTTh and enhanced responsivity by Au nanoparticles

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In this paper, novel self-powered p-n heterojunction UV photodetectors (TiO2 nanorod arrays/polyterthiophene (TiO2 NRs/PTTh) and TiO2 nanorod arrays/Au nanoparticles/polyterthiophene (TiO2 NRs/Au/PTTh)) are successfully constructed by combining the hydrothermal method and electrochemical deposition method. The structures, morphologies and photocurrent response properties of TiO2 NRs/PTTh and TiO2 NRs/Au/PTTh heterojunction UV photodetectors are systematically studied. These results show that TiO2 NRs/PTTh UV photodetector has self-powered performance, and also exhibit high sensitivity, good stability and fast response. Furthermore, the detection performance of UV photodetector could be further improved by using Au NPs as the middle layer due to the pyro-phototronic effect between Au NPs and TiO2 NRs. The responsivity (R) of TiO2 NRs/PTTh and TiO2 NRs/Au/PTTh UV photodetectors are respectively 0.0774 mA/W and 1.894 mA/W, and the detectability (D*) are respectively 2.155 × 109 Jones and 1.666 × 1010 Jones. Compared with the TiO2 NRs/PTTh UV photodetector, the rise time (τr) and fall time (τf) of TiO2 NRs/Au/PTTh UV photodetector are obviously shortened. And these results also confirm that the TiO2 NRs/Au/PTTh UV photodetector with heterojunction structure is a suitable candidate for self-powered UV photodetector. This work offers an effective strategy for the development of self-powered UV photodetectors.

P-n heterojunctionPolyterthiophenePyro-phototronic effectSelf-powered UV photodetectorTiO2 nanorod arrays

Zhang H.、Abdiryim T.、Li J.、Liu H.、Zou D.、Che Y.、Serkjan N.、Jamal R.、Kadir A.

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Institute of Applied Chemistry College of Chemistry Xin Jiang University

Key Laboratory of Petroleum and Gas Fine Chemicals Educational Ministry of China College of Chemical Engineering Xin Jiang University

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.899
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