Abstract
? 2022 Elsevier B.V.We report the influence of Ni substituting for Fe on the phase stability and thermoelectric properties of YbxFe4-yNiySb12 (x = 0.6, 0.7, 0.8, 0.9, 1.0; y = 1.0, 0.8, 0.6). Ni substituting can efficiently enhance phase stability but reduces band gap, which establishes an optimum Ni substituting content to keep the balance. Meanwhile, the atomic disorder caused by Ni substituting together with Yb-filling leads to a significant reduction in lattice thermal conductivity. The most marked reduction in lattice thermal conductivity is achieved in the Yb0.9Fe3.4Ni0.6Sb12 compound with a minimum value of 0.71 W m?1 K?1 at about 650 K. Finally, a peak zT of 0.85 is attained at 673 K in the Yb0.9Fe3.4Ni0.6Sb12 compound, which is comparable to other p-type skutterudites at the same temperature. This work highlights the importance of considering the competition between phase stability and band gap when designing high thermoelectric performance cobalt-free skutterudites.
NSTL
Elsevier