首页|(162899)Effect of co doping on the electric and dielectric properties of Bi_(3.8-x)Er_(0.2)Yb_xTi_3O_(12) lead-free ceramics
(162899)Effect of co doping on the electric and dielectric properties of Bi_(3.8-x)Er_(0.2)Yb_xTi_3O_(12) lead-free ceramics
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NSTL
Elsevier
The development of novel lead-free materials operating at high temperature and able to replace lead-based compounds and their derivatives in different devices is currently a remarkable challenge. In spite of having a high Curie temperature, the ferroelectric Bi_4Ti_3O_(12) is rarely used as a piezoelectric due to its high conductivity. In this work, Bi ions in Bi_4Ti_3O_(12) were partially replaced with Yb and Er aiming to compensate oxygen vacancies and improve others physical properties. In particular, Bi_(3.8-x)Er_(0.2)Yb_xTi_3O_(12) compounds with x = 0.05, 0.1, and 0.2 were prepared by a low-cost solid-solid state reaction process, and their structural, optical and electrical properties were investigated. It was observed that, at low temperatures, the conductivity, impedance and permittivity are mainly governed by grain effects, and by grain boundaries and grains effects at high temperatures. The electrical conductivity at 700 K decreases with Yb content and shows a minimum for x = 0.2. The relative permittivity at high temperatures is colossal while the tangent loss is negligible. High permittivities accompanied with low loss factor were obtained for Bi_(3.6) Er_(0.2)Yb_(0.2)Ti_3O_(12). These results open a wide application domain for this particular compound.
Bismuth titanateOptical band gapConductivityPermittivityOxygen vacancies
MA Wederni、W. Hzez、A. Rached
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Laboratoire de Physique des Materiaux et des Nanomateriaux appliquee a l'Environnement (LaPhyMNE), Faculte des Sciences de Gabes, cite Erriadh, Universite de Gabes, 6079 Gabes, Tunisia
L'institut Superieur des Sciences Appliquees et de Technologie de Gabes (ISSATG), Universite de Gabes, 6079 Gabes, Tunisia
NSTL
Elsevier
