首页|Kinetically induced one-step heterostructure formation of Co3O4-Ni(OH)2-graphene ternary nanocomposites to enhance oxygen evolution reactions
Kinetically induced one-step heterostructure formation of Co3O4-Ni(OH)2-graphene ternary nanocomposites to enhance oxygen evolution reactions
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NSTL
Elsevier
? 2022 Elsevier B.V.Ternary Co3O4-Ni(OH)2-graphene hybrid nanocomposites (NCs) can be fabricated using a facile, room-temperature kinetic spray process in a single step. The fabricated heterostructure electrodes are optimized to enhance the oxygen evolution reaction (OER) in 1.0 M KOH. The deposited films exhibit a mixture of nanosheet and nanoflake morphologies. Raman spectra reveal improvements in various disorder-related modes in the hybrid NCs due to the nanometer scale and the transformation of graphite-stacked layers into thin graphene nanosheets. X-ray photoelectron spectra indicate that strong synergy improvements in the heterostructure NCs are associated with a downshift of the active state's binding energies. Optimal Co3O4-Ni(OH)2-graphene hybrid ternary NCs exhibit the smallest OER overpotential of 262 mV @ 10 mA·cm?2, the lowest Tafel slope of 32 mV·dec?1, and long-term stability of 25 h at a polarization current of 50 mA·cm?2.
NSTL
Elsevier
