首页|Stable zero-thermal quenching cover wide temperature range achieves in cerium doped KY3F10 ultraviolet luminescent single crystal

Stable zero-thermal quenching cover wide temperature range achieves in cerium doped KY3F10 ultraviolet luminescent single crystal

扫码查看
? 2022 Elsevier B.V.Ce3+ ions (2 mol%) doped KY3F10 (Ce: KYF) single crystals were successfully grown by the vertical Bridgman method in a vacuum system. Ce3+: KYF single crystal had high crystalline quality and transmittance, and the absorption edge was significantly red shifted compared with undoped KYF. The broad band emission centered at 360 nm (λex = 300 nm) were both observed in them, while a three-fold increased emission intensity was seen when Ce3+ ions were doped. Ce: KYF crystal possessed high UV luminous efficiency due to converting the light of a 265 nm chip to its luminescence effectively. It was a surprise that Ce: KYF crystal exhibited stable zero-thermal quenching property in the UV band which covered a wide temperature range from 298 K to 573 K. The possible mechanism of the luminescent properties and the superior thermal stability of Ce: KYF was discussed. Ce: KYF single crystal will have good application prospect as an excellent UV luminescent material with high thermal stability.

Ce3+-doped KY3F10 single crystalIntrinsic defectsUltraviolet bandWide temperature rangeZero-thermal quenching

Li Z.、Tian T.、Yuan W.、Cui Q.、Zhang Y.、Gong Z.、Mao C.、Liu W.、Xu W.、Chu Y.、Liu L.、Xu J.、Yang B.

展开 >

Institute of Crystal Growth School of Materials Science and Engineering Shanghai Institute of Technology

School of Science Shanghai Institute of Technology

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.908
  • 4
  • 53