首页|Novel N, F co-doped carbon dots to detect sulfide and cadmium ions with high selectivity and sensitivity based on a "turn-off-on" mechanism

Novel N, F co-doped carbon dots to detect sulfide and cadmium ions with high selectivity and sensitivity based on a "turn-off-on" mechanism

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In this work, novel nitrogen, fluorine co-doped carbon dots (N, F-CDs) have been synthesized by a hydrothermal method using melamine and 2, 4-difluorobenzoic acid as precursors. The obtained N, F-CDs exhibit excellent optical stability with high quantum yield. The N, F-CDs are highly selective to S2- detection by forming N, FCDs@S2- , with a detection limit of 168 nM. The N, F-CDs@S2- were shown to be a highly selective Cd2+ detector by forming CdS, with a detection limit of 340 nM. The fluorescence quenching of N, F-CDs by S2- occurs via a static quenching mechanism and the fluorescence recovery was due to the high affinity of Cd2+ to S2-. The fluorescent sensor was used to determine Cd2+ and S2- in tap waters with satisfactory results.

Carbon dotFluorescent probeSulfide detectionCadmium detectionGRAPHENE QUANTUM DOTSHYDROGEN-SULFIDEPHOTOELECTROCHEMICAL IMMUNOASSAYFLUORESCENT SENSORGREEN SYNTHESISAQUEOUS-MEDIAPROBESGAS

Zhang, Mingming、Song, Jun、Zeng, Pengju、Qu, Junle、Guo, Jiaqing、Li, Hao、Zeng, Yutian、Xu, Zhibin、Liu, Aikun、Cai, Haojie

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Shenzhen Univ

2022

Dyes and Pigments

Dyes and Pigments

EISCI
ISSN:0143-7208
年,卷(期):2022.203
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