Palladium Complexes [Ph3PEt][PdBr3(DMSO)], [Ph3PCH2OMe][PdBr3(DMSO)], [Ph3PC5H9-cyclo][PdBr3(DMSO)], and [Ph3PCH2CH=CHCH2PPh3] [PdBr3(DMSO)]2: Synthesis and Structure

V. V. Sharutin O. K. Sharutina V. S. Senchurin

Russian Journal of Coordination Chemistry2022，Vol.48Issue(9) ：6.DOI:10.1134/S1070328422090044

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Pleiades Publishing Inc

Palladium Complexes [Ph3PEt][PdBr3(DMSO)], [Ph3PCH2OMe][PdBr3(DMSO)], [Ph3PC5H9-cyclo][PdBr3(DMSO)], and [Ph3PCH2CH=CHCH2PPh3] [PdBr3(DMSO)]2: Synthesis and Structure

V. V. Sharutin ¹O. K. Sharutina ¹V. S. Senchurin¹

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作者信息

1. South Ural State University (National Research University), Chelyabinsk, Russia
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Abstract

Ionic complexes of palladium(II) with mononuclear anions [Ph3PEt][PdBr3(DMSO)] (I), [Ph3PCH2OMe][PdBr3(DMSO)] (II), [Ph3PC5H9-cyclo][PdBr3(DMSO)] (III), and [Ph3PCH2CH= CHCH2PPh3][PdBr3(DMSO)]2 (IV) are synthesized from organyl triphenylphosphonium bromide and pal-ladium(II) bromide in the presence of hydrobromic acid. The structures of the complexes are determined by X-ray diffraction (CIF files CCDC nos. 2115506 (I), 2115228 (II), 888748 (III), and 2115007 (IV)). The complexes contain organyltriphenylphosphonium cations and [PdBr3(DMSO)] anions.

Key words

bromopalladate(II) anions/organyltriphenylphosphonium cations/dimethyl sulfoxide/X-ray diffraction studies

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出版年

2022

Russian Journal of Coordination Chemistry

SCI

ISSN：1070-3284

参考文献量35

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