首页|On the reactions of Cu(II/I)ATP complexes with methyl radicals
On the reactions of Cu(II/I)ATP complexes with methyl radicals
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NSTL
Elsevier
? 2022The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with ?CH3 in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These results were corroborated by DFT calculations of the relevant compounds.
Kornweitz H.、Saphier M.、Yardeni G.、Lerner A.、Meyerstein D.、Blahman A.、Maimon E.、Zilbermann I.
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Department of Chemical Sciences The Radical Research Center and the Schlesinger Family Center for Compact Accelerators Radiation Sources and Application Ariel University
Chemistry Department Nuclear Research Centre Negev
Chemistry Department Ben-Gurion University of the Negev
NSTL
Elsevier
