首页|Oxide-doped hierarchically porous carbon for high-performance supercapacitor

Oxide-doped hierarchically porous carbon for high-performance supercapacitor

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Suffering from a relatively low energy density, carbon-based supercapacitors are restricted in the practical applications for green energy. However, heteroatom-doped hierarchically porous carbon materials (HPCs) can deliver prominent electrochemical performance as an electrode material. Herein, we report a simple two-step method for the synthesis of oxide-doped HPC with an ultra-high specific surface area of 3043.3 m2 g?1. In a three-electrode system, the specific capacitance of the oxide-doped HPC is as high as 375 F g?1 at 1 A g?1. Also, an aqueous symmetric supercapacitor (AS) assembled with the oxide-doped HPC achieves a high specific capacitance of 353 F g?1 at 1 A g?1 and excellent rate performance of 84.9% capacitance retention with current density up to10 A g?1. Most importantly, the energy density of the AS in the 3 M KOH solution can reach up to 17.7 Wh kg?1 at a power density of 600 W kg?1. In 1 M Na2SO4 solution, the specific capacitance of the AS shows no decay after 5000 cycles at 5 A g?1. These results reveal that the as-prepared oxide-doped HPC has great potential as an electrode material to realize remarkable electrochemical performance in supercapacitors.

Heteroatom dopantHierarchically porous carbonHigh electrochemical performanceSymmetric supercapacitorUltra-high specific surface area

Lei X.、Pan F.、Wang S.、Xiong B.、Liu Y.、Fu Z.、Xiang B.、Lu Y.、Hua C.

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Hefei National Research Center for Physical Sciences at the Microscale Department of Materials Science & Engineering CAS Key Laboratory of Materials for Energy Conversion University of Science and Technology of China

University of Science and Technology of China

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.901
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