首页|Photoinduced electron transfer properties of 4-phenyl-Pyridine-JV-Oxide and its coordination compound
Photoinduced electron transfer properties of 4-phenyl-Pyridine-JV-Oxide and its coordination compound
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Photoinduced electron transfer (PET) with the formation of stable radicals plays an importance role in many areas. However, the discovery of new photoresponsive moieties is still a challenge. In this work, pyridine W-oxide group itself was demonstrated to possess photoinduced electron transfer (PET) property for the first time. The radical of 4-phenyl-pyridine-W-oxide (ppno), generated by PET from oxygen atom to 4-phenyl-pyridine part, remained stable in dark in air at least for two weeks. [ZnCl2(ppno)2], one ppno-based novel crystalline coordination compound, has two electron donors, chlorine and oxygen atoms. In particular, experimental and theoretical calculation results showed that oxygen atoms in [ZnCl2(ppno)2] have dual actions. Firstly, oxygen atom as electron-withdrawing group increased the electron accepting ability of 4-phenyl-pyridine. Then, oxygen atoms tiiemselves are rich in electrons and can act as electron donors. This is exactly why the performance of PET and radical yield and stability of [ZnCl2(ppno)2] much better than ppno. Thus, pyridine W-oxide group as an effective photoresponsive functional motif, whether by interspersion or by coordination, could construct various novel photoresponsive materials.
Pyridine N-oxide groupPhotoinduced electron transferFunctional motifCoordination compoundPhotochromism
Yong-Fang Han、Ning-Ning Zhang、Li Li
展开 >
StateyKey Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, PR China
School of Chemistry and Chemical Engineering, Linocheng University, liaocheng, Shandong, 252000, PR China
NSTL
