Tetrahedron letters2022,Vol.885.DOI:10.1016/j.tetlet.2021.153570

Visible light-mediated, high-efficiency oxidation of benzyl to acetophenone catalyzed by fluorescein

Liu, Xin Geng, Haoxing Zhu, Qing
Tetrahedron letters2022,Vol.885.DOI:10.1016/j.tetlet.2021.153570

Visible light-mediated, high-efficiency oxidation of benzyl to acetophenone catalyzed by fluorescein

Liu, Xin 1Geng, Haoxing 1Zhu, Qing1
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作者信息

  • 1. Zhejiang Univ Technol
  • 折叠

Abstract

An environmentally friendly aerobic oxidation of benzyl C(sp(3))-H bonds to ketones via selective oxidation catalysis was developed. Fluorescein is an efficient photocatalyst with excellent chemical selectivity. The reaction has a wide substrate scope, and a successful gram-scale experiment demonstrated its potential industrial utility. (C) 2021 Elsevier Ltd. All rights reserved.

Key words

Ketones/Fluorescein/Oxidation/Free radicals/Visible light/ALCOHOLS/COMPLEX/BONDS

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出版年

2022
Tetrahedron letters

Tetrahedron letters

CCR
ISSN:0040-4039
被引量2
参考文献量36
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