Abstract
Hydrocarbon generation from liptinite-rich coal is an important focus in petroleum geology as well as in coal geology. The confined pyrolysis experiment in gold tubes is an effective approach in assessing the hydrocarbon generation potential of coals. Xihu Sag is one of the most hydrocarbon-rich Cenozoic basins in the East China Sea Shelf Basin, and oil and gas are believed to be generated from Paleogene liptinite-rich coals. Coals from the Pinghu and Huagang formations of the Paleogene have a liptinite content mostly higher than 10%, and contain type II-III organic matter. The Hln^ values, H/C, and O/C ratios of these coals are in the range of 200-300 mg/g-TOC, 0.97 to 1.42, and 0.08 to 0.20, respectively. All these characteristics demonstrate good potential for these coals to generate oil. Experimental data show that the maximum cumulative yields of oil produced range from 122.74 to 154.09 mg/g-TOC, and the coals in the sag can also generate oil in their immature stage (Ro = 0.36%-0.5%) due to abundant resinite (mostly higher than 5%). To further assess the characteristics and processes of petroleum generation under geological conditions, we reconstructed the liquid hydrocarbon generation history of the coals in three structural units of Xihu Sag, i.e., the West Slope Belt, West Sub-sag, and Central Anticlinal Belt. For the coals in the Pinghu Formation, the West Slope Belt is a favorable oil-forming area, while the West Sub-sag and the Central Anticlinal Belt are less favorable oil-forming areas. For the coals in the Huagang Formation, the West Slope Belt is a favorable asphaltene (∑C_(14+)-forming area, while the West Sub-sag and Central Anticlinal Belt are favorable light hydrocarbon (∑C_(6-14)-forming areas. Results of this study will contribute to a better understanding of the characteristics and potential of oil generation from the liptinite-rich coals and are of significance for oil exploration in the Xihu Sag.
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