首页|(163055)Bi_2WO_6-wrapped 2D Ni-MOF sheets with significantly improved photocatalytic activity by a direct Z-scheme electron transfer

(163055)Bi_2WO_6-wrapped 2D Ni-MOF sheets with significantly improved photocatalytic activity by a direct Z-scheme electron transfer

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Constructing Z-scheme heterojunction is considered to be a promising strategy to isolate photogenerated carriers and boost the activity of the photocatalysts. Here in, a novel Z-scheme Bi_2WO_6/Ni-MOF heterojunction with intimate interface was constructed via wrapping flowerlike Bi_2WO_6 on 2D Ni-MOF sheets. The resultant Bi_2WO_6/Ni-M0F heterojunction displayed superior photocatalytic performance with respect to methylene blue degradation under visible light illumination. When the content of Ni-MOF was 20 wt%, the Bi_2WO_6/Ni-M0F heterojunction achieved the highest activity, which was 24.0 and 6.4 folds that of the pristine Ni-MOF and Bi_2WO_6, respectively. The superior degradation performance was caused by the formation of a direct Z-scheme heterostructure between Ni-MOF and Bi_2WO_6, which boosted the separation of photoinduced carriers. The principal active species and possible photocatalytic mechanism were also explored. This study provides a pathway to design and fabricate efficient Z-scheme photocatalysts for environmental remediation.

Bi_2WO_6/Ni-MOFZ-scheme heterostructure2D MOFPhotodegradation

Lin Cheng、Min Xie、Yitong Sun

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Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, PR China

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.896
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